Aluminum alloy forged material and method for manufacturing the same

ABSTRACT

Provided is an aluminum alloy forged material comprising an excess amount of Si and a large quantity of a strength-increasing element such as Cu or Mn, and by which high strength and high toughness can be stably obtained even if the forged material is thinned, and also provided is a method for producing the same. A forged material constituted from an aluminum alloy which contains prescribed quantities of Mg, Si, Cu, Fe, Ti and B and further contains one or more elements selected from among Mn, Cr and Zr, with the remainder comprising Al and inevitable impurities, wherein the electrical conductivity measured at 20° C. on the surface of the aluminum alloy is greater than 42.5% IACS but not more than 46.0% IACS, and the forged aluminum alloy material has 0.2% proof stress of 360 MPa or more and Charpy impact value of 6 J/cm 2  or more.

FIELD OF THE INVENTION

The present invention relates to an aluminum alloy forged material suitably used for strength members for transportation machines or the like, particularly chassis members of an automobile, and a method for manufacturing the same.

BACKGROUND OF THE INVENTION

Conventionally, aluminum alloys composed of 6000 series (Al—Mg—Si series) aluminum alloys according to the JIS standard or the AA standard, and the like, are used for structural materials or structural parts of transportation machines such as vehicles, ships, aircrafts, motorcycles, and automobiles. The 6000 series aluminum alloys have relatively excellent resistance to corrosion. The 6000 series aluminum alloys are also excellent in terms of their easy reusability of scraps as 6000 series aluminum alloy molten raw materials.

In view of decreasing production cost and workability to components of complicated structure, aluminum alloy cast materials and aluminum alloy forged materials are used for structural materials or structural parts of transportation machines. Among them, the aluminum alloy forged materials are used for structural members of automobiles, particularly for underbody parts such as upper arms and lower arms as they require mechanical properties including higher strength and toughness. Each of such aluminum alloy materials is produced by performing hot forging (die forging) such as mechanical forging or hydraulic forging after a homogenizing heat treatment of an aluminum alloy cast material, and then performing a tempering treatment including a solution-quenching treatment and an artificial aging treatment (sometime referred simply to aging treatment hereinafter). As a raw material for forging, besides the cast material mentioned above, an extruded material obtained by extruding a cast material after a homogenizing heat treatment may also be used.

In recent years, increasing requirements of further weight (thickness) reduction have been raised for strength members for the transportation machines due to higher demand of low fuel consumption and low CO₂ emission. It is difficult, however, for 6000 series aluminum alloy forged materials such as 6061 and 6151 alloys that have been conventionally used for the applications to realize the high enough strength (0.2% proof stress) and toughness.

In order to solve the problem, the present inventors proposed an aluminum alloy forged material described in Japanese Patent No. 3766357. Disclosed in the patent literature is an aluminum alloy forged material including Mg: 0.6-1.8 mass %, Si: 0.8-1.8 mass %, Cu: 0.2-1.0 mass %, mass ratio of Si/Mg is 1 or more, further including one or more of Mn: 0.1-0.6 mass %, Cr: 0.1-0.2 mass % and Zr: 0.1-0.2 mass %, and the remainder being Al and inevitable impurities. The aluminum alloy forged material of the composition has a thickness of the thinnest portion of 30 mm or less, electrical conductivity measured at the surface of 41.0-42.5% IACS after artificial aging treatment, and 0.2% proof stress of 350 MPa or more.

SUMMARY OF THE INVENTION Problems to be Solved by the Invention

However, when one attempts to mass produce an aluminum alloy forged material having a portion whose thickness is 10 mm or less, the one faces a problem that a forged material having high mechanical strength such as 0.2% proof stress of 360 MPa or more and high toughness cannot be obtained in a reproducible manner by using the aluminum alloy forged material disclosed in Japanese Patent No. 3766357.

In the mass production of 6000 series of aluminum alloy forged material, dispersions in various conditions of homogenizing heat treatment and hot forging can be usually accommodated to a certain extent. However, the dispersions in manufacturing conditions, which are usually accommodated, affect the 0.2% proof stress of an aluminum forged material if the mechanical strength of the forged material is enhanced so that the 0.2% proof stress is 360 MPa or more by containing an excess amount of Si as well as Cu and Mn which are added in an increased amount to enhance the mechanical strength of the thinned forged material. As a result, forged material of high mechanical strength and high toughness cannot be secured as the 0.2% proof stress of the products excessively varies even if the manufacturing conditions are within the specified range.

Such a poor reproducibility of a forged material of high mechanical strength and toughness damages reliability of the material for the use of strength members, reduces the manufacturing yield of the forged material product, and increases the manufacturing cost. Excessively narrow tolerances of the manufacturing conditions aiming to stabilize the 0.2% proof stress and toughness of the forged material also lead to increasing the manufacturing cost.

The present invention has been made in view of the above-mentioned problem. An object of the present invention is to stably provide an aluminum alloy forged material which exhibits increased mechanical strength and high toughness even if the forged aluminum alloy material is reduced in thickness, by containing an excess amount of Si and a high amount of a strength-increasing element such as Cu and Mn, and a method for manufacturing the same.

Means to Solve the Problem

The present invention to solve the above-mentioned problem is characterized in that the aluminum alloy forged material comprising: 0.60-1.80 mass % of Mg; 0.80-1.80 mass % of Si; 0.20-1.00 mass % of Cu; 0.05-0.40 mass % of Fe; 0.001-0.15 mass % of Ti; 1-500 ppm of B; further comprising one or more selected from 0.10-0.60 mass % of Mn, 0.10-0.40 mass % of Cr, and 0.10-0.20 mass % of Zr; and the remainder being Al and inevitable impurities, and the electrical conductivity measured at the surface of the aluminum alloy forged material at 20° C. is greater than 42.5% IACS but not more than 46.0% IACS, the 0.2% proof stress is 360 MPa or more, and the Charpy impact value is 6 J/cm² or more.

With the prescribed compositions and properties, mechanical strength and toughness of the aluminum alloy forged material are improved by containing the specific amounts of Mg, Si, Cu, Fe, Ti, and B, and further containing the specific amount of a strength-increasing element such as Mn, and by controlling the 0.2% proof stress and the Charpy impact value to the specific value or larger. The mechanical strength and toughness of the forged material are also improved by controlling the electrical conductivity measured at the surface of the aluminum alloy forged material to the specific range because the ratio of sub-grain structure is increased while maintaining the corrosion resistance.

Mass ratio of Si/Mg is preferably 1 or more in the aluminum alloy of the present invention. If the Si/Mg mass ratio is 1 or more, the 0.2% proof stress of the aluminum alloy forged material further increases.

Content of hydrogen gas is preferably 0.25 ml/100 g-Al or less in the aluminum alloy forged material. By controlling the content of hydrogen gas to the specified value or less, along with the aforementioned composition, forging defects such as bubbles from hydrogen are diminished. As a result of the decreased density of fracture starting points, the Charpy impact value of the aluminum alloy forged material is increased.

The method for manufacturing the aluminum alloy forged material according to the present invention is comprising: a melting step of melting the aluminum alloy into a molten metal, a casting step of casting the molten metal at a cooling rate of 10° C./sec or more to form an ingot, a homogenizing heat treatment step of subjecting the ingot to heating at a rate of 5° C./min or less, and to a homogenizing heat treatment at 450-550° C., a forging step of subjecting the ingot having been subjected to the homogenizing heat treatment to forging at 460-540° C. of the forging start temperature, and after the forging step, a solution heat treatment step of subjecting the forged material to a solution heat treatment at 520-570° C., and an artificial aging treatment step of subjecting the forged material to an artificial aging treatment at 170-200° C. for 4-9 hours.

According to the process described above, by conducting each of the step under the specific condition, particularly by carrying out the forging step at the starting temperature of 460-540° C., precipitation of Mg₂Si is enhanced because of increase of ratio of sub-grain structure and hence the grain boundaries in the forged structure. As a result, the electrical conductivity measured at the surface of the aluminum alloy forged material after the artificial aging treatment is controlled to the specific range.

The present inventors have conceived and found that by containing an excess amount of Si and an increased amount of Cu and Mn or the like, electrical conductivity measured at the surface of the aluminum alloy (sometimes referred to as surface electrical conductivity hereinafter) is more closely correlated with the 0.2% proof stress of the forged material in an aluminum alloy forged material which exhibits high mechanical strength of 0.2% proof stress of 360 MPa or more, even if the forged material is reduced in thickness.

If has been generally known that the surface electrical conductivity, reflecting the structure of an aluminum alloy, is closely correlated with the 0.2% proof stress of the aluminum alloy. It is not necessarily limited to 6000 series aluminum alloy forged material. However, in ordinary 6000 series aluminum alloy forged materials, the relation between electrical conductivity on the surface of aluminum alloy forged material and 0.2% proof stress is moderately linear. Unless the surface electrical conductivity drastically changes, 0.2% proof stress is not significantly influenced by the electrical conductivity in the ordinary 6000 series aluminum alloy forged materials.

On the other hand, in a 6000 series aluminum alloy forged material which is highly strengthened to the 0.2% proof stress of 360 MPa or more by containing an excess amount of Si and an increased amount of Cu and Mn or the like, even if the forged material is reduced in thickness, the 0.2% proof stress tends to be maximized if the surface electrical conductivity is more than 42.5% IACS but not more than 46.0% IACS. Moreover, the 0.2% proof stress shows peculiar characteristics of sharp decrease if the surface electrical conductivity is out of the range.

Therefore, in the 6000 series aluminum alloy forged material in which the 0.2% proof stress is increased to 360 MPa or more, and the thickness is reduced, the dispersions in electrical conductivity on the surface of the aluminum alloy forged material due to dispersions in manufacturing conditions more sensitively affect the 0.2% proof stress of the forged material. As a result, a forged material with 0.2% proof stress of 360 MPa or more is not stably produced due to the dispersion of the manufacturing conditions that are usually accommodated as described above.

According to the present invention, by utilizing the above-described phenomenon, 0.2% proof stress of 360 MPa or more in an Al alloy forged material can be secured and such material can be stably produced by controlling the surface electrical conductivity to more than 42.5% IACS but not greater than 46.0% IACS. In other words, by controlling the manufacturing condition so that the electrical conductivity is more than 42.5% IACS but not greater than 46.0% IACS on the surface of the aluminum alloy forge material, a forged material with 0.2% proof stress of 360 MPa or more can be stably produced.

Effect of the Invention

Provided by the present invention is an aluminum alloy forged material comprising an excess amount of Si and a large quantity of a strength-increasing element such as Cu or Mn, and by which high strength and high toughness can be stably obtained while maintaining the corrosion resistance even if the forged material is thinned, and also provided is a method for producing the same. The present invention therefore has considerable industrial significance as it expands the use of aluminum alloy forged material for transportation machines.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a front view of a test specimen used for measurements of tensile strength, 0.2% proof stress, and elongation.

FIG. 2 are (a) a front view, (b) a side view, and (c) a magnified view of the notched part of (b) of a test specimen to be used for Charpy impact test.

FIG. 3 show (a) a side view and (b) a front view of a test specimen used for stress corrosion test.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Firstly, the aluminum alloy forged material (referred to Al alloy forged material hereinafter) according to the present invention is explained. In the Al alloy forged material, electrical conductivity measured at 20° C. at the surface of the material after an artificial aging treatment which is described later is controlled to a range of greater than 42.5% IACS but not more than 46.0% IACS in order to secure and stably obtain 0.2% proof stress of 360 MPa or more.

(Electrical Conductivity at 20° C. of Greater than 42.5% IACS but not more than 46.0% IACS)

In a highly-strengthened Al alloy forged material in which the 0.2% proof stress is enhanced to 360 MPa or more even if the thickness of the material is reduced, by containing excess amount of Si and an increased amount of Cu and Mn or the like as for the present invention, 0.2% proof stress of 360 MPa or more can not be attained if the electrical conductivity at 20° C. measured at the surface is either 42.5% IACS or less, or more than 46.0% IACS.

The electrical conductivity of the Al alloy forged material shows a similar behavior not only at the surface but also within the bulk including the center portion. Because of convenience in measurement, the electrical conductivity at the surface of the Al alloy forged material is selected in the present invention.

Each of test specimen of Al alloy forged material for measurement of electrical conductivity is prepared from an Al alloy forged material after an artificial aging treatment by mechanical grinding the surface about 0.05 to 0.1 mm or by etching the surface about a few micrometers. The electrical conductivity at the surface is measured by using, for example, an Eddy current type electrical conductivity meter (AutoSigma 3000DL, manufactured by GE Inspection Technologies Japan). By leaving the meter with a probe, a standard specimen, and the Al alloy forged material specimen for measurement in the same inspection area so that temperature of the all are equal, it is confirmed prior to the measurement that temperature of the specimens is within a range of ±1° C. of the ambient temperature by a contact thermometer. In the present invention, a measured value at 20° C. or a conversion value is used to represent electrical conductivity of Al alloy forged material. Hereinafter, “electrical conductivity at 20° C.” is simply referred to as “electrical conductivity”.

The electrical conductivity on the surface of Al alloy forged material comprehensively reflects the contents of each of alloy elements as well as structure of the material including their dispersion and degree of crystallization. Further, in addition to these material factors, the electrical conductivity also reflects total metallurgical state of the material including factors in manufacturing conditions.

In an Al alloy forged material which is highly-strengthened to 0.2% proof stress of 360 MPa or more, even if the forged material is reduced in thickness, by containing an excess amount of Si and an increased amount of Cu and Mn or the like, the surface electrical conductivity is not necessarily the same even if the content of each alloying element or the process conditions such as temperature of homogenizing heat treatment and starting temperature of hot forging are roughly in accord with each other.

Influencing factors of manufacturing condition, which affect surface electrical conductivity of the Al alloy forged material after the artificial aging treatment include; in addition to the above-described temperature conditions, details of the cooling rate in the casting step, the heating rate, the holding temperature, and the cooling rate of ingot in the homogenizing heat treatment step, type of hot forging apparatus such as mechanical forging and hydraulic forging, number of times of the forging, working ratio in each of the forging steps, the condition of forging finish temperature, the temperature and time conditions of the solution heat treatment, the quenching treatment, and the artificial aging treatment.

This is because the surface electrical conductivity is significantly affected by slight difference in the process condition in an Al alloy forged material even if it is reduced in thickness as the forged material is highly-strengthened to 0.2% proof stress of 360 MPa or more by containing an excess amount of Si and an increased amount of Cu and Mn or the like.

Thus, if the conditions of material and manufacturing are roughly in accord and the surface electrical conductivities of the Al alloy forged materials are similar, then the problem to be solved by the present invention, the dispersion in the 0.2% proof stress in the mass-produced materials, would not arise.

According to the present invention, 0.2% proof stress is controlled to 360 MPa or more and Charpy impact value is controlled to 6 J/cm² or more in the Al alloy forged material.

(0.2% Proof Stress: 360 MPa or more, and Charpy Impact Value: 6 J/cm²)

By controlling the 0.2% proof stress to 360 MPa or more and the Charpy impact value to 6 J/cm² or more in the Al alloy forged material to possess high enough mechanical strength and toughness, it becomes possible to use the Al alloy forged material for structural material or parts for transportation machines such as an automobile and a ship.

Chemical components in the Al alloy forged material of the present invention are explained hereinafter. The Al alloy forged material of the present invention comprises Al—Mg—Si series (6000 series) Al alloy, and the chemical components are specified to secure high mechanical strength, high toughness, and high durability such as stress corrosion cracking resistance for the material to be used for structural material or structural parts for transportation machines such as an automobile and a ship. The chemical components in the Al alloy forged material of the present invention are ones of main factors to govern the electrical conductivity on the surface of the forged material.

The chemical composition of the aluminum alloy forged material of the present invention includes Mg: 0.60-1.80 mass %, Si: 0.80-1.80 mass %, Cu: 0.20-1.00 mass %, Fe: 0.05-0.40 mass %, Ti: 0.001-0.15 mass %, B: 1-500 ppm; further comprising one or more element selected from Mn: 0.10-0.60 mass %, Cr: 0.10-0.40 mass % and Zr: 0.10-0.20 mass %; and the remainder being Al and inevitable impurities, accordingly.

It is to be noted here that the chemical composition of the aluminum alloy forged material of the present invention may not necessarily be in accord with a standard component of 6000 series Al alloy of the JIS standard or the like. For the purpose of further improvement or additional properties, other kinds of element are allowed to be contained appropriately within a range which does not inhibit the characteristics of the present invention. In addition, inevitable impurities which are inevitably mixed from molten raw material scraps are also allowed within a range which does not inhibit the qualities of the forged material of the present invention.

Next, critical significance and preferred ranges of each element constituting the Al alloy forged material of the present invention are explained.

(Mg: 0.60-1.80 Mass %)

Mg is precipitated as Mg₂Si (β′ phase) in crystal grains together with Si by artificial aging treatment, and is an essential element for imparting the high 0.2% proof stress to the aluminum alloy forged material. When the content of Mg is less than 0.60 mass %, the amount of age hardening during the artificial aging treatment is decreased, resulting in deterioration of Charpy impact value (referred to as an index of toughness hereinbelow) and corrosion resistance which are essential properties for an Al alloy forged material as for the high 0.2% proof stress. On the other hand, when the content of Mg exceeds 1.80 mass %, the 0.2% proof stress is excessively increased to inhibit forging properties. Further, a large amount of Mg₂Si is liable to precipitate in the middle of a quenching step after a solution heat treatment as explained below. It hinders decrease of average grain size of the Mg₂Si and Al—Fe—Si—(Mn,Cr,Zr)-based crystallized and precipitated products residing on grain boundaries, which are formed by selective chemical bonding of Al, Si, Mn, Cr, Zr, and Fe, and suppresses average distance between the crystallized and precipitated products. As a result, the corrosion resistance of the Al alloy forged material is deteriorated. Moreover, when the content of Mg exceeds the specified range, it becomes difficult to control the electrical conductivity of the surface of the Al alloy forged materials to the range of greater than 42.5% IACS but not more than 46.0% IACS by adjusting the manufacturing conditions. Accordingly, the content of Mg is adjusted to the range from 0.60 to 1.80 mass %.

(Si: 0.80-1.80 Mass %)

Si is combined with Mg to form Mg₂Si (β′ phase) which precipitates during the artificial aging treatment. The precipitation of Mg₂Si crystals contributes to increasing 0.2% proof stress of the aluminum alloy forged material. When the Si content is less than 0.80 mass %, the amount of temper hardening decreases, and 0.2% proof stress and corrosion resistance of the Al alloy forged material are deteriorated. On the other hand, when the Si content exceeds 1.80 mass %, coarse single body Si particles are crystallized and precipitated in casting and in the middle of quenching after the solution heat treatment. Further, too much amount of the excessive Si prevents average grain size of the Al—Fe—Si—(Mn,Cr,Zr)-based crystallized and precipitated products residing on grain boundaries from decreasing, and suppresses average distance between the crystallized and precipitated products, resulting in deterioration of corrosion resistance and toughness of the Al alloy forged material, as for Mg. Furthermore, the excessive Si deteriorates the workability of the Al alloy forged material by lowering its elongation. Moreover, when the content of Si exceeds the specified range, it becomes difficult to control the electrical conductivity of the surface of the Al alloy forged materials to the range of greater than 42.5% IACS but not more than 46.0% IACS by adjusting the manufacturing conditions. The content of Si is to be 0.80-1.80 mass %, accordingly.

(Cu: 0.20-1.00 Mass %)

Cu contributes to enhancement of 0.2% proof stress for the material by solid solution strengthening. Furthermore, Cu has an effect to significantly promote age hardening of Al alloy forged material in the step of the artificial aging treatment. When the content of Cu is less than 0.20 mass %, these effects cannot be expected and 0.2% proof stress cannot be obtained. In order to secure these effects, the content of Cu is preferably controlled to 0.30 mass % or more. On the other hand, when the content of Cu exceeds 1.00 mass %, it extremely increases the sensitivity of stress corrosion cracking and intergranular corrosion of the structure of the aluminum alloy forged material, and deteriorates the corrosion resistance of the aluminum alloy forged material. Further, when the content of Cu exceeds the specified range, it becomes difficult to control the electrical conductivity of the surface of the Al alloy forged materials to the range of more than 42.5% IACS and 46.0% IACS or less by adjusting the manufacturing conditions. Therefore, the content of Cu is to be in the range of 0.20-1.00 mass %, and preferably 0.30-1.00 mass %.

(Fe: 0.05-0.40 Mass %)

Fe is added to improve the toughness of the Al alloy forged material. Fe forms Al₇Cu₂Fe, Al₁₂(Fe,Mn)₃Cu₂, (Fe,Mn)Al₆, and coarse Al—Fe—Si—(Mn,Cr,Zr)-based crystallized and precipitated products which is a problem to be solved by the present invention. These crystallized and precipitated products provide the start point of fracture and deteriorate the fracture toughness, fatigue properties and the like. In particular, if the content of Fe is more than 0.40 mass %, more strictly 0.35 mass %, then the Al—Fe—Si—(Mn,Cr,Zr)-based crystallized and precipitated products residing on grain boundaries become coarse, and average distance between the crystallized and precipitated products decreases, resulting in decrease of the toughness. If the content of Fe is less than 0.05 mass %, on the other hand, cracking during the casting step and abnormal material structure are induced. The content of Fe is to be in a range of 0.05-0.40 mass %, accordingly. The content of Fe is preferably to be in a range of 0.05-0.35 mass %.

(Ti: 0.001-0.15 Mass %)

Ti is added to the aluminum alloy to make crystal grains in the ingot finer to improve the workability of the material in the extrusion, rolling, and forging steps. If a content of Ti is less than 0.001 mass %, the effect of improved workability is not obtained. On the other hand, if the content of Ti is higher than 0.15 mass %, coarse precipitated crystalline particles are formed and the workability is deteriorated. The content of Ti is to be in a range of 0.001-0.15 mass %, accordingly.

(B: 1-500 ppm)

Like Ti, B is added to the aluminum alloy to make crystal grains in the ingot finer to improve the workability of the material in the extrusion, rolling, and forging steps. If a content of B is less than 1 ppm, the effect is not obtained. On the other hand, if the content of B is higher than 500 ppm, coarse precipitated crystalline particles are formed and the workability is deteriorated. The content of B is to be in a range of 1-500 ppm, accordingly.

(At Least One Element of Mn: 0.10-0.60 Mass %, Cr: 0.10-0.40 Mass %, and Zr: 0.10-0.20 Mass %)

These elements forms dispersed particles (dispersed phase) collectively known as (Fe,Mn,Cr,Zr)₃SiAl₁₂ system of Al—Mn, Al—Cr, and Al—Zr intermetallic compounds which precipitate by selective chemical bonding of Fe, Mn, Cr, Zr, Si, and Al or others according to their contents during the homogenizing heat treatment step and subsequent the hot forging step.

Since these dispersed particles have an effect of preventing grain boundaries from moving after recrystallization, coarsening of average crystal size in ST direction of parting line structure in the forging step is prevented. Fine crystal grains or fine sub grains are obtained as well throughout the Al alloy forged material according to the present invention. Further, enhancement of 0.2% proof stress is also expected by solid solution of Mn, Cr, and Zr.

The aluminum alloy according to the present invention contains one or more elements selected from Mn, Cr and Zr, within the range of the contents. If the content of Mn, Cr and Zr is too low, the effect cannot be expected. On the other hand, if an excessive amount of these elements is contained, coarse Al—Fe—Si—(Mn,Cr,Zr)-based intermetallic compounds or crystallized and precipitated products are liable to be formed in the middle of melting and casting steps. They behave as fracture starting points and are factors to deteriorate at least one of electrical conductivity, 0.2% proof stress, toughness, and corrosion resistance of the Al alloy forged material. Accordingly, the content of each of the elements is adjusted to the range of Mn: 0.10-0.60 mass %, Cr: 0.10-0.40 mass % and Zr: 0.10-0.20 mass %, and one or more kinds of them are to be contained.

(Inevitably Contained Impurities)

Elements such as Zn, Be, and V may be assumed inevitably contained in the aluminum alloy. Each of these elements may be contained as long as the amount is low enough not to affect the feature of the present invention. Specifically, an amount of each of these elements is to be 0.05 mass % or less and a total amount of these elements is to be 0.15 mass %.

(Si/Mg Mass Ratio: 1 or More)

Mass ratio of Si/Mg is preferably 1 or more in the aluminum alloy of the present invention. By controlling the Si/Mg mass ratio to 1 or more within the content of the elements the 0.2% proof stress further increases. If the Si/Mg mass ratio is less than 1, such enhancement of the 0.2% proof stress cannot be realized.

Further, the content of hydrogen in the Al alloy forged material of the present invention is preferably to be regulated to a range shown below.

(Hydrogen: 0.25 ml/100 g-Al or Less)

Especially when the working ratio of an Al alloy forged material is small, hydrogen (H₂) is liable to cause forging defects such as blow holes and the like caused by hydrogen, provides starting points of fracture, and therefore is liable to significantly deteriorate the toughness and fatigue properties of the forged material. The effect of hydrogen particularly becomes significant for the highly strengthened structural material of transportation devices. The content of hydrogen, therefore, is to be regulated to 0.25 ml/100 g-Al or less, and preferably as low as possible.

Next, the method for manufacturing the aluminum alloy forged material in relation with the present invention is explained. The manufacturing method in relation with the present invention includes a melting step, a casting step, a homogenizing heat treatment step, a forging step, and a tempering step. The Al alloy forged material of the present invention may be manufactured in a usual manner, other than controlling the surface electrical conductivity to the range of more than 42.5% IACS but not more than 46.0% IACS, the 0.2% proof stress, and the toughness of the Al alloy forged material. Explained hereinafter are conditions of each of the steps to improve the characteristics of the Al alloy forged material such as controlling the electrical conductivity within the specified range.

(Melting Step)

The melting step is a step to dissolve an aluminum alloy having the above-described composition into a molten metal.

(Casting Step)

The casting step is a step to cast the molten metal having the above-described composition into an ingot. Ordinal melting and casting method, such as continuous casting and rolling method, semi-continuous casting method (direct chill casting process), hot-top casting method, or the like is suitably selected and the ingot is casted. Shape of ingot is not particularly limited. It may be a round bar or a slab shape.

The molten alloy is cast to an ingot at a cooling rate of 10° C./sec or more for the purpose of refinement of crystal grains in the ingot, decreasing the mean crystal grain size of the Al—Fe—Si—(Mn,Cr,Zr)-based crystallized and precipitated products residing on grain boundaries, and increasing the average distance between the crystallized and precipitated products. If the cooling rate is low, the mean crystal grain size of the Al—Fe—Si—(Mn,Cr,Zr)-based crystallized and precipitated products residing on grain boundaries increases, and the average distance between the crystallized and precipitated products decreases, resulting in decrease of the 0.2% proof stress of the Al alloy forged material after an artificial aging treatment. It is noted that that the cooling rate of the molten alloy is defined as a mean cooling rate from the liquidus temperature to the solidus temperature.

(Homogenizing Heat Treatment Step)

The homogenizing heat treatment step is a step of subjecting the ingot to homogenizing heat treatment. The treatment is conducted at a heating rate of 5° C./min or less and at a holding temperature ranging from 450 to 550° C.

When the homogenizing heat treatment temperature is too high exceeding 550° C., the (Fe,Mn,Cr,Zr)₃SiAl₁₂ dispersed particles become coarse and the density decreases, failing to disperse relatively high density of fine dispersed crystals among the crystal grains and to obtaining fine crystal grains. As a result, the 0.2% proof stress of the Al alloy forged material is decreased after the homogenizing heat treatment.

On the other hand, of the holding temperature is too low, i.e., less than 450° C., the number of the (Fe,Mn,Cr,Zr)₃SiAl₁₂ dispersed precipitates decreases, causing a shortage of density of the dispersed grains. Further, sufficient solid solution of the Al—Fe—Si—(Mn,Cr,Zr)-based crystallized and precipitated products cannot be realized. It becomes difficult to decrease the mean grain size of Mg₂Si and Al—Fe—Si—(Mn,Cr,Zr)-based crystallized and precipitated products residing on grain boundaries in the Al alloy forged material after a tempering step explained later, and to increase the average distance between the crystallized and precipitated products. As a result, it becomes difficult to control the electrical conductivity of the surface of the Al alloy forged materials to the range of more than 42.5% IACS but not more than 46.0% IACS (hereinafter referred to the range of the present invention) after the artificial aging treatment.

The heating rate to the holding temperature is suppressed low as to 5° C./min. or less in order to maintain the 0.2% proof stress of the Al alloy forged material after the artificial aging treatment. Holding duration at the holding temperature is preferably 2 hours or more. For the homogenizing heat treatment, the air furnace, the induction heating furnace, a niter furnace, or the like is used appropriately. The heating rate of an ingot is defined as a mean heating rate from room temperature to the holding temperature.

(Forging Step)

The forging step is a step of using the above-mentioned ingot subjected to the homogenizing heat treatment as a forging raw material, and performing predetermined hot forging by forging using a mechanical press or by forging using a hydraulic press. For the hot forging, starting temperature of the forging raw material is adjusted to 460-540° C. If the starting temperature is less than 460° C., precipitation of Mg₂Si is suppressed because a ratio of sub-grain and the density of grain boundaries in the forged structure are decreased. As a result, the 0.2% proof stress is deteriorated as the electrical conductivity on the surface of the Al alloy forged material after the artificial aging treatment cannot be controlled within the range of the present invention. On the other hand, of the starting temperature is more than 540° C., there are cases in which a portion of the material melts because of heat generated during the forging step. As a result, the 0.2% proof stress and the corrosion resistance are deteriorated as the electrical conductivity cannot be controlled within the range of the present invention.

The finishing temperature of the forging raw material in the hot forging step is preferably to be 350-540° C. from a point of view to control the electrical conductivity to the range of the present invention. For the purpose of diminishing residual forged structure in the Al alloy forged material and further improvement of 0.2% proof stress and toughness, an ingot which has been extruded and/or rolled after a homogenizing heat treatment may also be used as a forging raw material.

In order to control the hot-forging finishing temperature to 350-540° C., it is necessary to exercise ingenuity such as reheating prior to hot forging and using a die which can be held at high temperatures.

For the purpose of facilitating to control the electrical conductivity on the surface of the Al alloy forged material after the artificial aging treatment to the range of the present invention, it is preferred to perform the hot forging by a mechanical forging method, and to perform the forging not more than three times. The shape of the Al alloy forged material is not particularly limited, and may be near net shape which is close to that of a final product.

(Heat Treatment Step)

A heat treatment step is a step of performing a solution treatment and an artificial aging treatment after the forging step, in order to obtain 0.2% proof stress, corrosion resistance, and toughness necessary for an Al alloy forged material. Specifically, the heat treatment step includes T6 (an artificial aging treatment for obtaining the maximum strength after the solution treatment at 520-570° C.), T7 (excessive artificial aging treatment (over-aging treatment) surpassing the conditions of the artificial aging treatment for obtaining the maximum strength after the solution treatment), T8 (an artificial aging treatment for obtaining the maximum strength, in addition to a cold forging after the solution treatment) or the like.

The solution heat treatment is conducted at a temperature range of 520-570° C. If the treatment temperature is excessively low, insufficient solutionizing prevents the solid solution of Mg₂Si, controlling the electrical conductivity to the specified range of the present invention, which results in decrease of 0.2% proof stress. If the treatment temperature is excessively high, localized melting and coarsening of crystal grains are induced, resulting in decrease of 0.2% proof stress. The holding duration and heating rate of the solution heat treatment are preferably 20 minutes to 20 hours and 100° C./hr or more, respectively, in order to secure the 0.2% proof stress. The heating rate of the Al alloy forged material is defined as a mean heating rate from the temperature of the material immersed in the solution to the holding temperature in the present invention.

A quenching step may be conducted after the solution heat treatment. The quenching treatment may be conducted by cooling in either cold or hot water. The cooling rate is preferably 40° C./sec or more in order to prevent degradation of toughness and fatigue property of the forged material. An air furnace, an induction heating furnace, a niter furnace, or the like is used appropriately.

Temperature and duration of the artificial aging step significantly affect the electrical conductivity on the surface of the Al alloy forged material after the artificial aging step. It is thus necessary to select appropriate conditions in the step by considering the process hysteresis of the material in order to secure the 0.2% proof stress by controlling the electrical conductivity within the range of the present invention as well as to secure the essential toughness and corrosion resistance. Depending on the amount of alloy elements and process hysteresis (manufacturing conditions) before the artificial aging treatment step, it is necessary to confirm in each of the processing step and manufacturing apparatus. In order to control the electrical conductivity on the surface of the Al alloy forged material after the artificial aging treatment into the range of the present invention, processing condition of the artificial aging treatment is selected from a range of temperature of 170 to 200° C. and a duration of 4 to 9 hours, considering the conditions aiming for the material having the maximum strength by the tempering treatments of T6, T7, and T8 steps. For the artificial aging treatment, the air furnace, the induction heating furnace, an oil bath, or the like is used appropriately.

Further, the manufacturing method according to the present invention preferably includes a degassing step between the melting step and the casting step.

(Degassing Step)

The degassing step is a step of removing a hydrogen gas (degassing treatment) from the above-mentioned molten metal of the aluminum alloy melted in the melting step, and controlling a hydrogen gas concentration in 100 g of the aluminum alloy to 0.25 ml or less. The removal of the hydrogen gas is performed in a holding furnace for adjusting the components of the molten metal, and removing inclusions by fluxing, chlorine refining, or in-line refining of the molten metal. Preferably, the hydrogen gas is removed by blowing an inert gas of argon or the like into the molten metal using SNIF (Spinning Nozzle Inert Floatation) or porous plugs (Japanese Unexamined Patent Application Publication No. 2002-146447) in an apparatus for removing the hydrogen gas.

Here, the determination of the hydrogen gas concentration is performed by measuring a hydrogen gas concentration in an ingot produced in the casting step described later or in a forging produced in the forging step, which is described later. The hydrogen gas concentration in the ingot can be obtained by, e.g., cutting a sample out of the ingot prior to the homogenizing heat treatment, subjecting the sample to ultrasonic cleaning using alcohol and acetone, and measuring the hydrogen gas concentration in the sample by, e g., the inert gas flow fusion-thermal conductivity method (LIS A06-1993). On the other hand, the hydrogen gas concentration in the forged material can be obtained by, e.g., cutting a sample out of the forging, immersing the sample in a NaOH solution, removing an oxide coating on the surface thereof with a nitric acid, subjecting the sample to ultrasonic cleaning using alcohol and acetone, and measuring the hydrogen gas concentration in the sample by the vacuum heating extraction volumetric method (LIS A06-1993).

In the manufacturing method of the present invention, a pre-forming step by forging roll or the like may be included prior to the forging step.

EXAMPLES

Next, the present invention is specifically described based on examples. Al alloy ingots of compositions shown in Table 1 were casted at a cooling rate of 20° C./sec by a hot-top casting method into a round bar of 68 mm in diameter and 580 mm in length. The ingots were then subjected to a homogenizing heat treatment at a heating rate of 5° C./min and a holding temperature of 550° C. for 4 hours.

Further, a hot forging was performed three times so that the total forging working ratio reaches 75% by a mechanical forging method using an upper and a lower dies at the forging start temperature and forging finish temperature shown in Table 2. Manufactured was an Al alloy forged material in a shape of chassis members of an automobile. The thinnest part of the forged material was 6 mm in thickness.

Next, the Al alloy forged material was subjected to a solution heat treatment at 550° C. for 1 hour in an air furnace, followed by a water cooling (water quenching) step. The forged material was subsequently subjected to an artificial aging treatment at 190° C. for 5 hours in an air furnace.

Three test pieces were collected from each of the specimens, and subjected to evaluations on electrical conductivity at the surface, tensile properties such as tensile strength, 0.2% proof stress, elongation, which are measures of mechanical strength, and Charpy impact value (mechanical property) which is a measure of toughness. Each of the values shown in Table 2 is an average value of those collected from the three test pieces. The measurements of tensile strength, 0.2% proof stress, elongation were conducted using test specimens S1 collected from each of the Al alloy forged material as shown in FIG. 1 and by a test method according to the provisions of JIS-Z-2241. The measurement of Charpy impact value was performed using test specimens S2 collected from each of the Al alloy forged material as shown in FIG. 2 and by a test method according to the provisions of JIS-Z-2242. The test pieces having 0.2% proof stress of 360 MPa or more and Charpy impact values of 6 J/cm² or more were each evaluated as excellent.

Test pieces S3 of a C-ring shape illustrated in FIG. 3 were also collected from each of the Al alloy forged material, and subjected to a stress corrosion cracking resistance test. The stress corrosion cracking resistance test was performed using the test pieces S3 in the C-ring shape and the alternate immersion test method according to the provisions of ASTMG47. Under added stress of 75% of the yield stress in LT direction of the test pieces S3, the C-ring shape test pieces were repeatedly subjected to a cycle of immersion and pulling into and out of a salt water during a test period of 90 days. Then presence/absence of stress corrosion cracking in each of the test pieces was examined. The test pieces which did not undergo cracking nor grain boundary corrosion including whole-surface corrosion on the surface were each provided with “good” representing excellent stress corrosion cracking resistance, and evaluated as having excellent corrosion resistance. The test pieces without stress corrosion cracking but with grain boundary corrosion which could potentially leads to stress corrosion cracking were each provided with “not very good” representing not very good stress corrosion cracking resistance, and evaluated as having not very good corrosion resistance. The test pieces which underwent cracking were each provided with “poor” representing poor stress corrosion cracking resistance, and evaluated as having poor corrosion resistance. The results are shown in Table 2.

TABLE 1 Al alloy composition Alloy (In mass %. Contents of B and H₂ are in ppm and ml/100 g-Al, respectively. The remainder being Al) No. Mg Si Cu Fe Ti B Mn Cr Zr Zn H₂ Si/Mg  1 1.00 1.10 0.50 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.10  2 0.60 0.80 0.20 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.33  3 0.60 0.80 0.20 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.33  4 1.80 1.80 1.00 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.00  5 1.80 1.80 1.00 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.00  6 1.00 1.10 0.50 0.20 0.03 50 0.5 — — 0.01 0.15 1.10  7 1.00 1.10 0.50 0.20 0.03 50 — 0.15 — 0.01 0.15 1.10  8 1.00 1.10 0.50 0.20 0.03 50 — — 0.10 0.01 0.15 1.10  9 1.00 1.10 0.50 0.20 0.03 50 0.5 0.15 — 0.01 0.15 1.10 10 1.00 1.10 0.50 0.20 0.03 50 — 0.15 0.10 0.01 0.15 1.10  1A 1.00 0.80 0.50 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 0.80  1B 1.00 0.90 0.50 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 0.90  1C 1.00 0.80 0.50 0.20 0.03 50 0.5 0.15 0.10 0.01 0.26 0.80  1D 1.00 1.10 0.50 0.20 0.03 50 0.5 0.15 0.10 0.01 0.26 1.10 13 0.50 1.80 1.00 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 3.60 14 2.00 1.80 1.00 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 0.90 15 1.80 0.70 1.00 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 0.39 16 1.80 2.00 1.00 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.11 17 1.80 1.80 0.10 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.00 18 1.80 1.80 1.20 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.00 19 1.90 1.90 1.10 0.20 0.03 50 0.5 0.15 0.10 0.01 0.15 1.00 20 1.00 1.10 0.50 0.20 0.03 50 — — — 0.01 0.15 1.10 21 1.00 1.10 0.50 0.20 0.03 50 0.7 0.15 0.10 0.01 0.15 1.10 22 1.00 1.10 0.50 0.20 0.03 50 0.5 0.42 0.10 0.01 0.15 1.10 23 1.00 1.10 0.50 0.20 0.03 50 0.5 0.15 0.22 0.01 0.15 1.10 24 1.00 1.10 0.50 0.20 0.03 50 0.7 0.42 0.30 0.01 0.15 1.10 25 1.00 1.10 0.50 0.45 0.03 50 0.5 0.15 0.10 0.01 0.15 1.10 26 1.00 1.10 0.50 0.03 0.03 50 0.5 0.15 0.10 0.01 0.15 1.10 27 1.00 1.10 0.50 0.20 0.17 50 0.5 0.15 0.10 0.01 0.15 1.10 28 1.00 1.10 0.50 0.20 0.03 600  0.5 0.15 0.10 0.01 0.15 1.10 29 1.00 1.10 0.50 0.20 — — 0.5 0.15 0.10 0.01 0.15 1.10 Note that underlined values indicate that they are out of the claimed range specified in Claim 1. “—” represents the element is not contained in the alloy specimen.

TABLE 2 Casting Homogenizing Tempering step Alloy step heat treatment step Solution Solution Artificial Artificial Properties of Al alloy forged material No. Cooling Heating Heat Forging step heat heat aging aging Surface 0.2% Charpy Stress in rate rate Holding treatment Starting Finishing treatment treatment treatment treatment electrical Tensile proof impact corrosion Table (° C./ (° C./ temp. time temp. temp. temp. time temp. time conductivity stress stress Elongation value cracking No. 1 sec) min) (° C.) (hr) (° C.) (° C.) (° C.) (hr) (° C.) (hr) (% IACS) (MPa) (MPa) (%) (J/cm²) resistance Examples  1  1 20 5 550 4 500 420 550 1 190 5 44.0 400 380 14 15 good  2  2 20 5 550 4 540 460 550 1 190 5 45.5 395 368 16 20 good  3  3 20 5 550 4 460 380 550 1 190 5 45.0 386 363 15 18 good  4  4 20 5 550 4 540 460 550 1 190 5 43.0 425 400 12 11 good  5  5 20 5 550 4 460 380 550 1 190 5 42.7 420 395 10 10 good  6  6 20 5 550 4 500 420 550 1 190 5 44.5 400 375 12 13 good  7  7 20 5 550 4 500 420 550 1 190 5 45.0 390 370 12 13 good  8  8 20 5 550 4 500 420 550 1 190 5 44.5 395 375 12 13 good  9  9 20 5 550 4 500 420 550 1 190 5 44.5 393 375 13 14 good 10 10 20 5 550 4 500 420 550 1 190 5 44.5 396 375 13 14 good 10A  1 20 5 550 4 500 420 550 1 170 4 42.9 397 378 15 16 good 10B  1 20 5 550 4 500 420 550 1 180 4 43.0 402 383 15 15 good 10C  1 20 5 550 4 500 420 570 1 190 5 42.6 410 380 13 14 good 10D  5 20 5 550 4 460 380 550 1 170 4 42.6 418 393 11 10 good 10E  1A 20 5 550 4 500 420 550 1 190 5 44.7 385 365 15 17 good 10F  1B 20 5 550 4 500 420 550 1 190 5 44.3 390 373 14 16 good 10G  1C 20 5 550 4 500 420 550 1 190 5 44.7 380 362 10  7 good 10H  1D 20 5 550 4 500 420 550 1 190 5 44.0 395 375 10  8 good Comparative 11 13 20 5 550 4 500 420 550 1 190 5 43.5 400 380 8  5 not very examples good 12 14 20 5 550 4 500 420 550 1 190 5 41.4 435 415 7  6 poor 13 15 20 5 550 4 500 420 550 1 190 5 43.5 375 358 9  6 not very good 14 16 20 5 550 4 500 420 550 1 190 5 41.5 430 410 6  5 poor 15 17 20 5 550 4 500 420 550 1 190 5 43.5 375 350 10 10 good 16 18 20 5 550 4 500 420 550 1 190 5 41.6 440 425 6  6 poor 17 19 20 5 550 4 500 420 550 1 190 5 41.5 440 420 6  5 poor 18 20 20 5 550 4 500 420 550 1 190 5 45.0 370 345 9  9 good 19 21 20 5 550 4 500 420 550 1 190 5 42.0 375 355 10  9 good 20 22 20 5 550 4 500 420 550 1 190 5 44.5 370 340 12 10 not very good 21 23 20 5 550 4 500 420 550 1 190 5 44.5 365 330 10  9 not very good 22 24 20 5 550 4 500 420 550 1 190 5 42.0 360 325 8  7 good 23  1  5 5 550 4 500 420 550 1 190 5 45.0 370 340 9 13 good 24  1 20 10  550 4 500 420 550 1 190 5 43.0 370 340 9 12 good 25  1 20 5 560 4 500 420 550 1 190 5 45.0 370 345 9 12 good 26  1 20 5 550 4 420 350 550 1 190 5 42.4 375 355 10  9 good 27  1 20 5 550 4 550 470 550 1 190 5 46.6 320 300 4  7 not very good 28  1 20 5 550 4 500 420 510 1 190 5 46.5 350 320 13 12 good 29  1 20 5 550 4 500 420 550 1 220 5 46.5 350 320 7  9 good 30 25 20 5 550 4 500 420 550 1 190 5 43.0 390 370 9  5 good 31 26 20 5 550 4 Forging could not be conducted due to cracking in the casting step. 32 27 20 5 550 4 500 420 550 1 190 5 43.0 400 380 10  5 good 33 28 20 5 550 4 500 420 550 1 190 5 43.5 400 380 11  5 good 34 29 20 5 550 4 Cracking occurred in the forging step due to coarsening of the casted structure. Note that underlined values indicate that they are out of the claimed range specified in Claims 1 and 4.

As shown in Tables 1 and 2, Al alloy forged material examples Nos. 1-10, 10A-10H were excellent in terms of 0.2% proof stress, Charpy impact value, and stress corrosion cracking resistance, satisfying the scope of claims of the present invention. On the other hand, Al alloy forged material comparative examples Nos. 11-34 did not satisfy the scope of claims of the present invention, and are inferior in terms of either 0.2% proof stress, Charpy impact value, or stress corrosion cracking resistance.

Specifically, comparative example No. 11 was inferior in terms of the Charpy impact value and the stress corrosion crack resistance because the content of Mg was less than the lower limit. Comparative example No. 12 was inferior in terms of the stress corrosion crack resistance and the electrical conductivity was less than the lower limit because the content of Mg was more than the upper limit. Comparative example No. 13 was inferior in terms of the 0.2% proof stress and the stress corrosion crack resistance because the content of Si was less than the lower limit. Comparative example No. 14 was inferior in terms of the Charpy impact value and the stress corrosion crack resistance and the electrical conductivity was less than the lower limit because the content of Si was more than the upper limit. Comparative example No. 15 was inferior in terms of the 0.2% proof stress because the content of Cu was less than the lower limit. Comparative example No. 16 was inferior in terms of the stress corrosion crack resistance and the electrical conductivity was less than the lower limit because the content of Cu was more than the upper limit. Comparative example No. 17 was inferior in terms of the Charpy impact value and the stress corrosion crack resistance and the electrical conductivity was less than the lower limit because the contents of Mg, Si, and Cu were more than each of the upper limit.

Comparative example No. 18 was inferior in terms of the 0.2% proof stress because it did not contain either Mn or Cr or Zr. Comparative example No. 19 was inferior in terms of the 0.2% proof stress and the electrical conductivity was less than the lower limit because the content of Mn was more than the upper limit. Comparative example No. 20 was inferior in terms of the 0.2% proof stress and the stress corrosion crack resistance because the content of Cr was more than the upper limit. Comparative example No. 21 was inferior in terms of the 0.2% proof stress and the stress corrosion crack resistance because the content of Zr was more than the upper limit. Comparative example No. 22 was inferior in terms of the 0.2% proof stress and the electrical conductivity was less than the lower limit because the contents of Mn, Cr, and Zr were more than each of the upper limit.

Although the chemical components satisfy the claimed range, comparative example No. 23 was inferior in terms of the 0.2% proof stress because the cooling rate was less than the lower limit. Although the chemical components satisfy the claimed range, comparative example No. 24 was inferior in terms of the 0.2% proof stress because the heating rate was more than the upper limit. Although the chemical components satisfy the claimed range, comparative example No. 25 was inferior in terms of the 0.2% proof stress because the duration in the homogenizing heat treatment step was more than the upper limit. Although the chemical components satisfy the claimed range, comparative example No. 26, which is the Al alloy forged material according to the invention of Japanese Patent No. 3766357, was inferior in terms of the 0.2% proof stress because the forging start temperature was less than the lower limit and hence the electrical conductivity became less than the lower limit. Although the chemical components satisfy the claimed range, comparative example No. 27 was inferior in terms of the 0.2% proof stress and the resistance to stress corrosion cracking because the forging start temperature was more than the upper limit and hence the electrical conductivity became more than the upper limit. Although the chemical components satisfy the claimed range, comparative example No. 28 was inferior in terms of the 0.2% proof stress because the temperature of the solution heat treatment was less than the lower limit and hence the electrical conductivity became more than the upper limit. Although the chemical components satisfy the claimed range, comparative example No. 29 was inferior in terms of the 0.2% proof stress because the temperature of the artificial aging treatment was more than the upper limit and hence the electrical conductivity became more than the upper limit.

Comparative example No. 30 was inferior in terms of the Charpy impact value because the content of Fe was more than the upper limit. Cracking occurred and comparative example No. 31 could not be forged because the content of Fe was less than the lower limit. Comparative example No. 32 was inferior in terms of the Charpy impact value because the content of Ti was more than the upper limit. Comparative example No. 33 was inferior in terms of the Charpy impact value because the content of B was more than the upper limit. Comparative example No. 34 cracked during the forging step because the cast structure became coarse as it did not contain Ti and B. 

1. An aluminum alloy forged material comprising Al and Mg: from 0.60 to 1.80 mass %; Si: from 0.80 to 1.80 mass %; Cu: from 0.20 to 1.00 mass %; Fe: from 0.05 to 0.40 mass %; Ti: from 0.001 to 0.15 mass %; B: from 1 to 500 ppm; and at least one element selected from Mn: from 0.10 to 0.60 mass %, Cr: from 0.10 to 0.40 mass % and Zr: from 0.10 to 0.20 mass %; wwherein the electrical conductivity measured at the surface of the aluminum alloy forged material at 20° C. is greater than 42.5% IACS but less than or equal to 46.0% IACS, the 0.2% proof stress is greater than or equal to 360 MPa, and the Charpy impact value is greater than or equal to 6 J/cm².
 2. The aluminum alloy forged material according to claim 1, wherein the mass ratio of Si/Mg is greater than or equal to
 1. 3. The aluminum alloy forged material according to claim 1, wherein a hydrogen concentration is 0.25 ml/100 g-Al or less.
 4. A method for manufacturing the aluminum alloy forged material according to claim 1, the method comprising: melting the aluminum alloy into a molten metal, casting the molten metal at a cooling rate of 10° C./sec or more to form an ingot, subjecting the ingot to heating at a rate of 5° C./min or less, and to a homogenizing heat treatment at 450-550° C. to form a homogenized ingot, forging the homogenized ingot, wherein the forging start temperature is from 460 to 540° C., and subjecting the forged homogenized ingot to a solution heat treatment at 520-570° C. to form a forged ingot, and subjecting the forged ingot to an artificial aging treatment at 170-200° C. for 4-9 hours to produce the aluminum alloy forged material.
 5. The aluminum alloy forged material according to claim 2, wherein a hydrogen concentration is 0.25 ml/100 g-Al or less.
 6. A method for manufacturing the aluminum alloy forged material according to claim 2, the method comprising: melting the aluminum alloy into a molten metal, casting the molten metal at a cooling rate of 10° C./sec or more to form an ingot, homogenizing the ingot to heating at a rate of 5° C./min or less, and a homogenizing heat treatment at 450-550° C. to form a homogenized ingot, forging the homogenized ingot at 460-540° C. at the forging start temperature, subjecting the forged homogenized ingot to a solution heat treatment at 520-570° C. to form a forged ingot, and subjecting the forged ingot to an artificial aging treatment at 170-200° C. for 4-9 hours to produce the aluminum alloy forged material.
 7. An aluminum alloy forged material comprising Al and Mg: from 0.60 to 1.80 mass %; Si: from 0.80 to 1.80 mass %; Cu: from 0.30 to 1.00 mass %; Fe: from 0.05 to 0.35 mass %; Ti: from 0.001 to 0.15 mass %; B: from 1 to 500 ppm; and at least one element selected from Mn: from 0.10 to 0.60 mass %, Cr: from 0.10 to 0.40 mass % and Zr: from 0.10 to 0.20 mass %; wherein the electrical conductivity measured at the surface of the aluminum alloy forged material at 20° C. is greater than 42.5% IACS but less than 46.0% IACS, the 0.2% proof stress is greater than or equal to 360 MPa, and the Charpy impact value is greater than or equal to 6 J/cm². 